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A Study of Alkyl Chain Conformational Changes in Self-Assembled n -Octadecyltrichlorosilane Monolayers on Fused Silica Surfaces

โœ Scribed by Liu, Yi; Wolf, Lauren K.; Messmer, Marie C.


Book ID
120827307
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
559 KB
Volume
17
Category
Article
ISSN
0743-7463

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The surface of colloidal silica of 22 nm and 100 nm in diameter has been modified with a silane coupling agent, n-octadecyltriethoxysilane. The solid state 13C NMR spectrum shows surprisingly that the covalently bonded n-octadecyl chains on the silica surface adopt largely extended all-rrans confor