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A study of adsorption of some bicyclo [2.2.1] heptane derivatives on graphitized thermal carbon black

✍ Scribed by E.V. Kalashnikova; A.V. Kiselev; R.S. Petrova; K.D. Shcherbakova

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 509 KB
Volume: 25
Category: Article
ISSN: 0001-8686
DOI: 10.1016/0001-8686(86)80008-2

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✦ Synopsis

Retention volumes at zero sample size (Henry's constants of adsorption equilibrium), Kovats' indices and the changes in differential molar internal energy and entropy upon adsorption are found for bicyclo[2.2.l]heptane (norbornane), six isomeric dimethylnorbornanes and 7,7'-bisnorbornane by gas adsorption chromatography on packed columns with GTCB. A molecular statistical calculation of the thermodynamic characteristics of adsorption is carried out and the results are compared with experimental data.

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