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A structure and reactivity analysis of monomeric Ni(ii)–hydroxo complexes prepared from water

✍ Scribed by Powell-Jia, Darla; Ziller, Joseph W.; DiPasquale, Antonio G.; Rheingold, Arnold L.; Borovik, A. S.


Book ID
117994282
Publisher
Royal Society of Chemistry
Year
2009
Tongue
English
Weight
251 KB
Volume
16
Category
Article
ISSN
1477-9226

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✍ Silvio Fallab; Margareta Zehnder; Ulf Thewalt 📂 Article 📅 1980 🏛 John Wiley and Sons 🌐 German ⚖ 413 KB

## Abstract Oxygenation of solutions containing bis(ethylenediamine) cobalt(II) ions leads to a mixture of diastereomeric forms of μ‐peroxo‐μ‐hydroxo‐bis[bis(ethylenediamine) cobalt(III)] cations. The existence of a meso‐isomer has now been proved by its isolation as perchlorate and by an X‐ray str