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A structural isomer of peltogynol trimethyl ether; 3-hydroxycoumaran-2-spiro-3′-isochromans, a new class of synthetic leuco-anthocyanidins.

✍ Scribed by J.W. Clark-Lewis; D.C. Skingle


Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
132 KB
Volume
7
Category
Article
ISSN
0040-4039

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✦ Synopsis


Reduction of the flavcme (Is), m.p. 287', with lithium aluminium hydride in ether has been found to yield 3-hydrolrycoumeran-2-m J'-isoohroman (3_hsdM~-4,5,5',6'-tetrahsdro_2,~benzo~~-5-~ 6t-3',41-benao-21H-pyran)(IIa), m.p. 171-172', and the 7-methaxyflavone (lb), m.p. 291-292', and trimethaay snalogue (Ic), m.p. 322', were similarly converted into the spirans (III, and IIc), m.ps. 169-170'


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