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A Structural Investigation by 13C-NMR of the Cyanogenic Glycosides

✍ Scribed by Winfried Hübel; Adolf Nahrstedt; Victor Wray

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
377 KB
Volume
314
Category
Article
ISSN
0365-6233

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✦ Synopsis

Abstract

^13^C‐NMR spectra of 20 cyanogenic glycosides have been measured in deuterium oxide. These compounds constitute representative examples of four groups of glycosides, namely the butyronitrile, propionitrile, mandelonitrile and cyclopentenoncyanohydrin glycosides. The well resolved signals in the proton‐decoupled ^13^C‐spectra are assigned and the potential of this method for characterizing and identifying this type of compound is demonstrated. The subtle effects upon the shifts caused by configuration change in the aglycon moiety are demonstrated to be of use in determining absolute configurations.

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