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A Straightforward Hetero-Diels–Alder Approach to (2-ambo,4′R,8′R)-α/β/γ/δ-4-Thiatocopherol

✍ Scribed by Stefano Menichetti; Riccardo Amorati; Maria Grazia Bartolozzi; Gian Franco Pedulli; Antonella Salvini; Caterina Viglianisi


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
399 KB
Volume
2010
Category
Article
ISSN
1434-193X

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ChemInform Abstract: Asymmetric Hetero D
✍ R. BADORREY; C. CATIVIELA; M. D. DIAZ-DE-VILLEGAS; J. A. GALVEZ 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB 👁 2 views

Asymmetric Hetero Diels-Alder Reaction of N-Benzylimines Derived from ( R)-Glyceraldehyde: A New Approach to Homochiral Piperidine Building Blocks and Its Application to the Synthesis of (2R)-4-Oxopipecolic Acid. -The D-glyceraldehyde derived N-benzyl imine (I) undergoes a highly diastereoselective