A Stopped-Flow Kinetic Study of the Reaction oftrans-1-(Dimethylamino)-1,3-butadiene with Dimethyl Dicyanofumarate

Kinetic and equilibrium studies of σ-add

Kinetic and equilibrium studies of σ-adduct formation and nucleophilic substitution in the reactions of morpholine with 1,3,5-trinitrobenzene and some phenyl aryl ethers in dimethyl sulphoxide

✍ Rachel A. Chamberlin; Michael R. Crampton; Ian A. Robotham 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 429 KB 👁 1 views

Reactions of morpholine in dimethyl sulphoxide at unsubstituted ring positions of 1,3,5-trinitrobenzene, and phenyl 2,4,64rinitrophenyl ether, yield anionic a-adducts via zwitterionic intermediates. Reactions at the 1- position of phenyl 2,4,64rinitrophenyl ether, phenyl 2,4-dinitronaphthyl ether, a