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A stereospecific total synthesis of (±)-epipentenomycin I, (±)-epipentenomycin II and (±)-epipentenomycin III

✍ Scribed by Amos B. Smith III; Nancy N. Pilla

Book ID
103406855
Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
253 KB
Volume
21
Category
Article
ISSN
0040-4039

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Synthesis of (±) epipentenomycin I and I
Synthesis of (±) epipentenomycin I and III
✍ Weerachai Phutdhawong; Stephen G. Pyne; Apiwat Baramee; Duang Buddhasukh; Brian 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 101 KB

A synthesis of (±) epipentenomycin I and III is reported from a regioselective epoxidation of racemic 3-hydroxy-and 3-acetoxy-2-methylene-4-cyclopentenone, respectively, with dimethyldioxirane followed by hydrolytic ring-opening of the resulting epoxide.