Tandem Wagner-Meerwein rearrangement-car
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Scott M. Starling; Simone C. Vonwiller
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Article
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1997
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Elsevier Science
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French
⚖ 231 KB
Ortho fithiated protected anilines and phenols undergo exclusive addition to fenchone from the exo face. The corresponding adducts, under acidic conditions undergo cationic rearrangement followed by internal trapping of the new cation with amino, hydroxyl or methoxyl substitueats to give enantiomefi