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A stereoselective synthesis of naturally occurring (+)-20R-dihydrocleavamine by photo-[2+2]-cycloreversion

✍ Scribed by Regina Mikie Kanada; Kunio Ogasawara


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
69 KB
Volume
42
Category
Article
ISSN
0040-4039

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## Abstract The synthesis of 9,10‐dimethoxy‐2‐methyl‐1,4‐anthraquinone, an unusual quinone, was achieved in five steps from __p__‐benzoquinone. A Kochi–Anderson radical methylation features as the key step in the synthesis. The chemistry of a cyclopropa‐1,4‐anthracenedione is also described. (© Wil