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A Stereoselective Synthesis of (±)-cis-γ-Irone

✍ Scribed by Cornelius Nussbaumer; Georg Fráter

Book ID
102258268
Publisher
John Wiley and Sons
Year
1988
Tongue
German
Weight
348 KB
Volume
71
Category
Article
ISSN
0018-019X

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✍ Daniel Helmlinger; Georg Fráter 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 German ⚖ 412 KB

Cyclobexene (&)-3 is completely stable when treated with ZnC1, in CH2C12, but obviously, it is not stable when butynone is also present. Probably, the proton necessary for isomerisation (see also [ll]) originates from the complex between butynone and ZnC1,.