A stereodivergent approach to carbahexofuranoses: synthesis of carba-α-d-glucofuranose, carba-β-d-altrofuranose, carba-α-d-allofuranose, carba-β-d-idofuranose, carba-α-d-galactofuranose and carba-β-d-talofuranose
✍ Scribed by Mukund G. Kulkarni; Ajit S. Borhade; Yunnus B. Shaikh; Attrimuni P. Dhondge; Deekshaputra R. Birhade; Nagorao R. Dhatrak
- Book ID
- 113929833
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- French
- Weight
- 415 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
Four carbasugars, 5a-carba-b-D-manno-, a-D-allo-, b-L-taloand a-L-gulopyranose pentaacetates, have been prepared in a stereodivergent manner from D-mannose. Alkynyl derivatives of 2,3:4,6-di-O-isopropylidene-D-mannopyranose, which are prepared by homologation at C-1, by reaction with phenyl acetylid
## Abstract For Abstract see ChemInform Abstract in Full Text.
A stereodivergent approach to 5a-carba-D-and L-pyranoses has been applied to the preparation of 5a-carba-a-D-gluco-, 5a-carba-a-D-galacto-, and 5a-carba-b-L-gulopyranose pentaacetates. The strategy, by which a single precursor can be transformed into three different carbasugars, features a stereosel