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A stereocontrolled route to a synthon for the aglycone of the aureolic acids

✍ Scribed by Richard W. Franck; C.S. Subramaniam; Thomas V. John; John F. Blount

Book ID: 104233568
Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 245 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81199-0

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✦ Synopsis

Cyclohexenone 3, a synthon for the aureolic acid aglycone, has been prepared usi.ng D-fucose and trimethylsilyloxvbutad.iene as starting materials.

The aureolic acid group of antitumor antibiotics is comprised of mithramycin, the chromomycins, the olivomycins and variamycin. 1 The synthesis of their agly-

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