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A Stereocontrolled Access to α-C-(1→3)-Linked Disaccharides Containing 2-Deoxyhexopyranoses.

✍ Scribed by Petr Stepanek; Ladislav Kniezo; Hana Dvorakova; Pavel Vojtisek


Publisher
John Wiley and Sons
Year
2003
Weight
113 KB
Volume
34
Category
Article
ISSN
0931-7597

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α-(1 → 2)-, α-(1 → 3)-, and α-(1 → 6)-Li
✍ Robert N. Comber; Joyce D. Friedrich; David A. Dunshee; Sandra L. Petty; John A. 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 877 KB

The syntheses of several alpha-linked thioglycosidic disaccharides are described, including thiokojibiose octaacetate (1), thionigerose (2), and thioisomaltose (3). The title compounds were synthesized by coupling 2,3,4,6-tetra-O-acetyl-1.5-acetyl-1-thio-alpha-D-glucopyranose (4) with either 1,3,4,6