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A Square-Planar Ruthenium(II) Complex with a Low-Spin Configuration

✍ Scribed by Bjorn Askevold; Dr. Marat M. Khusniyarov; Dr. Eberhardt Herdtweck; Prof. Dr. Karsten Meyer; Dr. Sven Schneider

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
343 KB
Volume
49
Category
Article
ISSN
0044-8249

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Low spin-high spin planar Ni(II) complex
Low spin-high spin planar Ni(II) complexes with phosphinic amidato ligands
✍ Hans Josef Mink; Hans-Herbert Schmidtke 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 449 KB

The bis(di-tert-butylphosphinic-N-tert-pentyl-amidato-N, O) Ni(II) complex is planar and has a spin triplet of low energy (300-400 cm-l) close to the singlet ground state. The measured absorption spectrum exhibits two ligand field bands in the near-infrared and some other features in the visible whi