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A spectroscopic study of the protonation of acylferrocenes

✍ Scribed by H.E. Rubalcava; J.B. Thomson

Book ID
104333120
Publisher
Elsevier Science
Year
1962
Weight
518 KB
Volume
18
Category
Article
ISSN
0371-1951

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✦ Synopsis

Abstrac~---Tnfrared spectra of the products formed in the reaction between hydrogen chloride (and deuterium chloride) and the bases formylferroeene, acetylferrocene and 1,2-(a-ketotetramethylene)-ferrocene have been studied. The results suggest that these bases are much stronger than arylketones with a related skeletal structure and that at least two cationic conjugate acids are formed. The importance of the mutual interaction of the iron and oxygen atoms in stabilizing the protonated complexes is discussed.

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