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A spectroscopic study of some substituted tris(diimine) complexes of ruthenium(II) and their reduction products

โœ Scribed by R.J. Donohoe; C.D. Tait; M.K. DeArmond; D.W. Wertz

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
927 KB
Volume
42
Category
Article
ISSN
1386-1425

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The surface-enhanced Raman spectrum (SERS) of 2,2'-bipyridine (bpy) in DMF solvent as a function of exciting line indicates that the enhancement peaks with excitation near 19 X IO3 cm-'. Also, a shift in vibrational frequencies occurs as the potential is varied from -0.8 to -1.8 V versus AglAgCI, wi