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A spectroscopic and computational study of stereochemistry in 2-hydroxymutilin

โœ Scribed by Frederick G. Vogt; Grant P. Spoors; Qiaogong Su; Yemane W. Andemichael; Huan Wang; Thomas C. Potter; Douglas J. Minick

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
469 KB
Volume
797
Category
Article
ISSN
0022-2860

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## Abstract Anionic polymerization of 2โ€vinylpyridine shows significant solvent effects on the polymer stereochemistry. Polymerization with butyllithium in tetrahydrofuran (THF) yields a largely isotactic polymer, while polymerization with butyllithium in tetramethylโ€ethylenediamine (TMEDA) results