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A Solvent Effect in the Reaction of Diazomethane with Norbornane-2,3-dione 3-Hemiketals

✍ Scribed by Rao, G. Hari Mangeswara; Khan, Faiz Ahmed

Book ID
126645481
Publisher
Taylor and Francis Group
Year
2014
Tongue
English
Weight
322 KB
Volume
44
Category
Article
ISSN
0039-7911

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## Abstract Relative rates of [4 + 2] cycloadditions of cyclopentadienes 1a–1e with 4‐phenyl‐1,2,4‐triazoline‐3,5‐dione (2) in 12 different solvents vary by factors of up to 19000, but the reactions show similar solvent effects. Rate constants __k__~2~ correlate well with solvent parameters __AN__