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A Solid-State NMR, X-ray Diffraction, and Ab Initio Investigation into the Structures of Novel Tantalum Oxyfluoride Clusters

✍ Scribed by Alam, Todd M.; Clawson, Jacalyn S.; Bonhomme, François; Thoma, Steven G.; Rodriguez, Mark A.; Zheng, Shaohui; Autschbach, Jochen


Book ID
126317976
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
503 KB
Volume
20
Category
Article
ISSN
0897-4756

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Solid-state (23) Na NMR spectra of two organometallic complexes, cyclopentadienylsodium (CpNa) and the tetrahydrofuran (THF) solvate of CpNa (CpNa·THF), are presented. Analytical simulations of experimental spectra and calculated (23) Na electric-field gradient (EFG) tensors confirm that both comple