199Hg-NMR Spectroscopy was applied to study Hg-oxade ceramic l~gh temperature superconductors at room temperature. Spectra of samples with different macro-structure and transition-temperatures have been measured. A spin-spin relaxation time of T2 = 1.6 msec and a spin-lattice relaxation tune of T~ =
A solid-state 199Hg NMR study of mercury halides
β Scribed by R.E. Taylor; Shi Bai; C. Dybowski
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 583 KB
- Volume
- 987
- Category
- Article
- ISSN
- 0022-2860
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The solvation of the mercury(II) ion in solvents with different solvation properties, water, dimethylsulfoxide, N,N-dimethylthioformamide, and liquid ammonia, has been studied by means of 199 Hg NMR. The 199 Hg chemical shift shows a pronounced dependence on the coordination number of the mercury(II
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