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A single mode of DNA base-pair opening drives imino proton exchange

✍ Scribed by Guéron, Maurice; Kochoyan, Michel; Leroy, Jean-Louis

Book ID
109749898
Publisher
Nature Publishing Group
Year
1987
Tongue
English
Weight
475 KB
Volume
328
Category
Article
ISSN
0028-0836

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✍ Y. Z. Chen; W. Zhuang; E. W. Prohofsky 📂 Article 📅 1991 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 829 KB

Modified self-consistent phonon theory when applied to the DNA double helix indicates the existence of fairly long-lived states in which single interbase H bonds are disrupted. One can then postulate a number of situations in which particular disrupted H bonds can enhance particular proton exchange.