A simple three-descriptor model for the prediction of the glass-transition temperatures of vinyl polymers
β Scribed by Xinliang Yu; Wenhao Yu; Xueye Wang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 91 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0021-8995
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π SIMILAR VOLUMES
We describe an original QSPR model called the EVM model (Energy, Volume, Mass) to calculate the glass transition temperature (T g ) of aliphatic acrylate and methacrylate homopolymers using classical molecular mechanics and dynamics. The latter was used to calculate an energy density function relate
The effect of dissolved carbon dioxide on the glass transition temperature of a polymer, PMMA, has been investigated using molecular probe chromatography. The probe solute was iso-octane, and the specific retention volumes of this solute in pure PMMA and mixtures of PMMA with CO 2 were measured over