A simple synthesis of dl-chalcose
β Scribed by Danishefsky, Samuel; Kerwin, James F.
- Book ID
- 120791182
- Publisher
- American Chemical Society
- Year
- 1982
- Tongue
- English
- Weight
- 279 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0022-3263
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
In the previous papers 1)2) concerning the synthesis of muscarines, we reported a partially stereospecific synthesis in which the hydroxyl group of a diacid (I) was introduced selectively in trans manner to the methyl group. Decarboxylation of I, however , proceeded non-stereoselectively giving a m
7] a ) Satiafdctory elemental analyses were obtained for D -3 to 0-6 [Route The threo-dipropenylglycol DL-I, which is obtained by (a)] and I ) -/ L -~ [Route (b)]; b) due to difficulties in purification of such reductive dimerization of crotonaldehvde["l and simDle compounds and uncertainties in the