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A simple synthesis of dialkylketones from alkenes via hydroboration-carbenoidation

โœ Scribed by C. Narayana; M. Periasamy


Book ID
104236600
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
262 KB
Volume
26
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Hydroboration of alkenes

with sodium acetoxyborohydride(NaBH30Ac) followed by carbenoidation


๐Ÿ“œ SIMILAR VOLUMES


Organoboranes for synthesis. 7. An impro
โœ Herbert C Brown; Kee-Won Kim; Morris Srebnik; Singaram Bakthan ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 665 KB

Trforganylboranes, R3B, and diorganylborinic esters, R2BOR', re--readily with preformed chloramine or hydroxylamine-0-sulfonic acid to produce the corresponding primary amines, RNH2. However, the product of the reaction following hydrolysis is the boronic acid, RB(oH)2, limiting the yield to 67% for