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A simple synthesis of B-2-(1-trimethylsilyl-1-alkyl)-1,3,2-dioxaborinanes. Isolation and selective oxidation to 1-trimethylsilyl-1-alkanols

โœ Scribed by Narayan G. Bhat; Amanda Garza


Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
134 KB
Volume
44
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Simple procedures for the preparation of
โœ Narayan G Bhat; Claudia P Aguirre ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 67 KB

Two simple procedures for obtaining (Z)-2-(1-trimethylsilyl-1-alkenyl)-1,3,2-dioxaborinanes based on 1-trimethylsilyl-1-alkynes are described. In the first procedure, 1-trimethylsilyl-1-alkynes are hydroborated with diisopinocampheylborane to provide the corresponding (Z)-2-(trimethylsilyl-1-alkenyl

A highly diastereoselective synthesis of
โœ Narayan G. Bhat; Laura Garcia; Victoriano Tamez Jr. ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 98 KB

A convenient, novel synthesis of alkyl cyclopropyl ketones based on Z-1-bromo-1-alkenylboronate esters is developed. a-Bromo-(Z)-1-alkenylboronate esters readily available from literature procedures smoothly undergo a reaction with cyclopropylmagnesium bromide in tetrahydrofuran to provide the corre