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A simple synthesis of aminoazapolycyclic compounds via a photochemically induced cyclization reaction of 3-amino-2-alkene imines in an acid medium

✍ Scribed by Pedro J Campos; Elena Añón; M Carmen Malo; Miguel A Rodríguez

Book ID
104208917
Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
451 KB
Volume
54
Category
Article
ISSN
0040-4020

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✦ Synopsis

We describe the synthesis of benzo-, dibenzo-and naphthoquinolines substituted by aikyl-, arylamino or a NH2 group from irradiation of 3-naphthyl-and 3phenanthryl-2-alkene imines under mild reaction conditions. This reaction is suitable for the preparation of four-ring aminoazapolycyclic compounds containing a nonaromatic ring. The compounds obtained can potentially be used in medicinal chemistry.

📜 SIMILAR VOLUMES

ChemInform Abstract: A Simple Synthesis
ChemInform Abstract: A Simple Synthesis of Aminoazapolycyclic Compounds via a Photochemically Induced Cyclization Reaction of 3-Amino-2-alkene Imines in an Acid Medium.
✍ P. J. CAMPOS; E. ANON; M. C. MALO; M. A. RODRIGUEZ 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

A Simple Synthesis of Aminoazapolycyclic Compounds via a Photochemically Induced Cyclization Reaction of 3-Amino-2-alkene Imines in an Acid Medium. -Irradiation of alkene-imines such as (I), (III), (V), and (VII) in the presence of HBF 4 permits the synthesis of aminoazapolycyclic compounds under mi

A versatile synthesis of pyrrolo-, furo-
A versatile synthesis of pyrrolo-, furo- and thienopyridines via photocyclization of 3-amino-2-alkene imines in an acid medium
✍ Pedro J. Campos; Elena Añón; M.Carmen Malo; Miguel A. Rodríguez 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 422 KB

We describe the synthesis of pyrrolo-, furo-and thieno[3,2-b]pyridines substituted by alkyl-, arylamino or NH2 groups from irradiation of 2-pyrrolyl-, 2furyl-, and 2-thienylalkene imines under mild reaction conditions. We also describe the irradiation of 3-pyrrolyl-, 3-furyl-, and 3-thienylalkene im