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A simple synthesis of 4-substituted 2,3-benzoxazinones from C-2 arylated 1,3-indanediones

โœ Scribed by Suven Das; Pradyot Koley; Animesh Pramanik


Publisher
Elsevier Science
Year
2011
Tongue
French
Weight
713 KB
Volume
52
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


A simple one-pot procedure for the conversion of 2-hydroxy-2-(2 0 -hydroxy-aryl)-1,3-indanediones to 4substituted benzoxazinones has been developed. The process constitutes an interesting acid-catalyzed rearrangement followed by condensation with hydroxylamine.


๐Ÿ“œ SIMILAR VOLUMES


Simple Synthesis of Substituted 1,2,3-Tr
โœ Prof. Dr. H. J. Roth; H. George; F. Assadi; Dr. H. J. Rimek ๐Ÿ“‚ Article ๐Ÿ“… 1968 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 133 KB ๐Ÿ‘ 2 views

To form the radical by oxidation, the substance is shaken with a ten-fold excess of active PbO;! in benzene for 10 min. On rapid removal of the solvent, the reddish-brown solution affords an impure, reddish-brown paramagnetic product.