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A Simple Synthesis of 1,3,4-Thiadiazole

✍ Scribed by Dr. B. Föhlisch; cand. chem. R. Braun; Dipl.-Chem K. W. Schultze


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
218 KB
Volume
6
Category
Article
ISSN
0044-8249

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Synthesis of 3-Phenyl-, 3,4-Diphenyl-, a
✍ Dr. V. Bertini; Prof. Dr. P. Pino 📂 Article 📅 1965 🏛 John Wiley and Sons 🌐 English ⚖ 117 KB 👁 1 views

Acyl chlorides are split into acyl and chlorine radicals by light of wavelength 254 my. Since the dissociation energy of the chlorine-hydrogen bond is considerably larger than that of the acyl-hydrogen bond, substitution of the substrate by acyl radicals is observed on irradiation of acid chlorides.