It has been found that enolizable ketones and 1,3-diones react in neutral or basic medium with biselectrophiles such as 2-chloroselenobenzoyl chloride. The reaction takes place on the active a-methylene group. Selenenylation and subsequent acylation of the a-carbon atom take place and, depending on
✦ LIBER ✦
A Simple Route to Benzo[ b ]thiophenes: Sulfanylation–Acylation of C─H Acids with 2-(Chlorosulfanyl)benzoyl Chloride
✍ Scribed by Młochowski, Jacek; Potaczek, Piotr
- Book ID
- 120988663
- Publisher
- Taylor and Francis Group
- Year
- 2009
- Tongue
- English
- Weight
- 162 KB
- Volume
- 184
- Category
- Article
- ISSN
- 1042-6507
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