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A simple relationship between the nuclear magnetic shielding tensor and the electronic g tensor

✍ Scribed by Roger A. Hegstrom

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
355 KB
Volume
36
Category
Article
ISSN
0009-2614

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✦ Synopsis

A simptc, rxzct equation whick csprrsscs ;i fund~menIai relations~lip bctwen the electronicg tensor and the nuclear magnetic shlclding tensor is obtained for a one-electron system. This equation is used to predict new numerical values for the components of thcg tensor for Hs.

The nuclear magnetic shieldin:: tensor u and the electronicg tensor are quantities well known in magnetic resonance spectroscopy. The purposes of this letter are (1) to point out an exact, simple relationship between u and g for a one-electron atom or molecule in an orbitally non-degenerate state, and (2) to use this relationship to predict new numerical values for the components of the ,o 'tensor for the h'$ molecule4on.

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