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A Simple Protocol for the Generation of Methyl(trifluoromethyl)dioxirane.

✍ Scribed by Rossella Mello; Maria Elena Gonzalez-Nunez; Gregorio Asensio


Publisher
John Wiley and Sons
Year
2007
Weight
26 KB
Volume
38
Category
Article
ISSN
0931-7597

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The solvent-dependent shift in the regioselectivity of the ge-allylic alcohols, additional steric interactions control the Ο€facial selectivity in the conformationally fixed transition raniol epoxidation by methyl(trifluoromethyl)dioxirane (TFD) reveals that as for the less reactive dimethyldioxirane

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CM19 5AW (UK) [\*\*] We are grateful to GlaxoSmithKline for the provision of a CASE studentship (C.E.A. ). We also acknowledge the provision of a Leverhulme Trust grant which initiated our studies in this area. We also thank Dr. Grant Wishart (Wolfson Institute of Biomedical Research) for his help