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A simple procedure for evaluating the heterogeneity parameter and the ratio of molecular sizes of solute and solvent by using HPLC data

โœ Scribed by Dawidowicz, A. ;Jaroniec, M.


Publisher
John Wiley and Sons
Year
1982
Tongue
English
Weight
389 KB
Volume
5
Category
Article
ISSN
0935-6304

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โœฆ Synopsis


Abstract

Based on the relationship defining the dependence of the capacity ratio upon the composition of the mobile phase, a simple numerical procedure is proposed for evaluating the heterogeneity parameter and the ratio of molecular sizes of solute and solvent. This procedure is examined by using HPLC data for pesticides chromatographed in isooctane/dichloromethane eluent on Lichrosorb at 291 K.


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