In the course of recent investigations '-4 in this series, we developed a oneflask synthesis of triacetalated, acyclic aldohexoses by use of 2,2-dialkoxypropanes or l,l-dialkoxycyclohexanes in the presence of p-toluenesulfonic acid. As shown in a preceding paper', one of the triacetals obtained from
A simple preparation of the 2,3:5,6- and 3,4:5,6-di-O-isopropylidene derivatives of d-glucose dimethyl acetal
β Scribed by John D. Stevens
- Book ID
- 108308830
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 629 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0008-6215
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The structures of the title compounds (2b and 3) have been investigated in the solid state by X-ray methods. The crystals of 2b are monoclinic, space group P2,, and of 3 orthorhombit, space grtup P2,2,2,. The cell dimensions are: for 2b, a = 9.910(2), b = 11;745W, c = 11.810(3) A, /3 = 97.32(l)"; a
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