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A simple method to determine the anomeric configuration of sialic acid and its derivatives by 13C-NMR

✍ Scribed by Hiroshi Hori; Tatsuo Nakajima; Yoshihiro Nishida; Hirosbi Ohrui; Hiroshi Meguro

Publisher: Elsevier Science
Year: 1988
Tongue: French
Weight: 255 KB
Volume: 29
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)82335-7

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✦ Synopsis

The anomeric configuration of sialic acid and its derivatives could be determined on the basis of the coupling pattern of C-l in the gated proton-decoupled or selective proton decoupled "C-NMR spectra; the a! anomer gave a doublet C-l signal while the fi gave a singlet.

Recently much interest has been taken in the chemistry and biochemistry of sialic acids (a! 1 and fi 1) and the related compounds 1). Determination of

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