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A simple method for the preparation of various 1-oxo-hydrindene-2-acetic and -propionic acids. Valuable precursors of strigol and its analogues

✍ Scribed by István Kádas; Géza Árvai; Lászlo Tőke; Gábor Tóth; Áron Szöllősy; Mária Bihari

Book ID: 104204310
Publisher: Elsevier Science
Year: 1994
Tongue: French
Weight: 898 KB
Volume: 50
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)87001-0

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✦ Synopsis

Abrtra~t: An improved annulaiion sequence is presented, making use of the one-pot cyclization of S-nitqentan-2one and cyclopeni-2-enone diesters to aflord 7-methyl-4-nitro-l-oxohydrindene derivatives. Functional group elaborations of these intermediates lead to a series of the title compounds, which could be readily converted to the tricyclic moieties of strigol and its analogaes of biological importance.

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