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A Simple Method for the Electrophilic Cyanation of Secondary Amines

✍ Scribed by Zhu, Chen; Xia, Ji-Bao; Chen, Chuo

Book ID
121405242
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
734 KB
Volume
16
Category
Article
ISSN
1523-7060

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✍ Tohru Fukuyama; Mui Cheung; Chung-Kuang Jow; Yuko Hidai; Toshiyuki Kan πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 191 KB

2,4-Dinitrobenzenesulfonamides, readily prepared from primary amines and 2,4-dinitrobenzenesulfonyl chloride, can be alkylated by the Mitsunobu reaction or by the conventional methods to give N,N-disubstituted sulfonamides in excellent yields. Since 2,4-dinitrobenzenesulfonamides can be removed with