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A simple method for extending the range of pseudo-order kinetic measurements

✍ Scribed by James L. Jensen; Richard C. Kanner; Gregory R. Shaw

Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
376 KB
Volume
22
Category
Article
ISSN
0538-8066

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✦ Synopsis

Data are presented demonstrating the validity of a new method of measuring pseudo-order rate constants, based on an iterative computational procedure long in use for kinetic conditions where the "infinity" value is not experimentally accessible. This new method requires that the kinetic order be known for the limiting reagent, but is otherwise general. It allows measurement of the pseudo-order rate constant even at a ratio of reactants of 1: 1 by maximizing the fit of three half-lives of data to the appropriate pseudo-order kinetic equation, treating the "infinity" value as a variable.

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