A Simple Route to Acylsilane En01 Esters from En01 Esters skpbeil w. Wright During the course of some recent work on silyl kttene acetals, we sought to prepare the trimetbylsilyl ketene acetal of vinyl 2-etbylbexanoate. To our surprise, the attempted conversion of this compound to the trimethylsilyl
โฆ LIBER โฆ
A Simple Dialkylated Enol
โ Scribed by Dr. H. M. R. Hoffmann; Dr. E. A. Schmidt
- Book ID
- 101545990
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 234 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
โฆ Synopsis
observed a surprising reaction involving uncatalyzed hydrogen transfer from these amines containing a-hydrogen atoms to the aromatic nitrile group with formation of two imine groups. Besides ( I ) , it is so far known that 5-nitroanthranilonitrile (2-amino-5-nitrobenzonitrile) and its N,Ndibenzoyl derivative undergo this reaction.
' CGN
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