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A simple construction of chiral fused benzoxocine ring ethers from D-glucose by regioselective 8-endo-aryl radical cyclisation

โœ Scribed by Chattopadhyay, Partha; Mukherjee, Monika; Ghosh, Soma


Book ID
121412132
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
56 KB
Volume
22
Category
Article
ISSN
1359-7345

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Synthesis of chiral trans-fused pyrano[3
โœ Aniruddha Nandi; Partha Chattopadhyay ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 95 KB

A simple chiral synthesis of trans-pyrano [3,2-c][2]benzoxocines 8a-d in good yields (60-75%) through regioselective 8-endo-trig aryl radical cyclization of the D-mannose derived enopyranosides 7a-d with Bu 3 SnH is described.