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A simple cobalt catalyst system for the efficient and regioselective cyclotrimerisation of alkynes

✍ Scribed by Hilt, Gerhard; Vogler, Thomas; Hess, Wilfried; Galbiati, Fabrizio

Book ID
120585438
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
177 KB
Volume
11
Category
Article
ISSN
1359-7345

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## Abstract The palladacycle [Pd(__k__^__2__^__‐C__,__N__‐Cο£Ύ(C~6~H~5~)C(Cl)CH~2~NMe~2~)(μ‐Cl)]~2~ (1) derived from the chloropalladation of 3‐(dimethylamino)‐1‐phenyl‐1‐propyne and its phosphine adduct [Pd(__k__^__2__^__‐C__,__N__‐Cο£Ύ(C~6~H~5~)C(Cl)CH~2~NMe~2~)P(4‐CF~3~C~6~H~4~)~3~(Cl)] (3) promote