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A Simple C 2 Symmetric Sulfide for a One Pot Ylide Mediated Asymmetric Conversion of Aldehydes into Epoxides

✍ Scribed by Julienne, Karine; Metzner, Patrick; Greiner, Alfred; Henryon, Vivien

Book ID
126738160
Publisher
Taylor and Francis Group
Year
1999
Tongue
English
Weight
109 KB
Volume
153
Category
Article
ISSN
1042-6507

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πŸ“œ SIMILAR VOLUMES

Asymmetric synthesis of epoxides from ar
Asymmetric synthesis of epoxides from aromatic aldehydes and benzyl halides catalyzed by C2 symmetric optically active sulfides having a binaphthyl skeleton
✍ Yoshihiro Miyake; Arihiro Oyamada; Yoshiaki Nishibayashi; Sakae Uemura πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 148 KB πŸ‘ 1 views

## Abstract Reactions of aromatic aldehydes with benzyl bromide or iodide in the presence of a catalytic amount (10 mol%) of a C~2~ symmetric sulfide having a binaphthyl skeleton afford the corresponding trans‐stilbene oxides in moderate to good yields with moderate enantioselectivities (up to 55%