The intramolecular charge-transfer model for the electronic structure of amides has been extended to include the effects of torsion about the peptide bond (Au = w -180) and pyramidalization at the peptide nitrogen (ON). The model is used to calculate the absorption and CD spectra of nonplanar amides
โฆ LIBER โฆ
A simple approach for describing the optical properties of conjugated polymers
โ Scribed by H. Hartmann; K. Linsenbarth
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 322 KB
- Volume
- 219
- Category
- Article
- ISSN
- 0022-2860
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The optical absorpt,ion and circular dichroisin (CD) of poly-1.-alariine in an a-helical conformation are computed in terms of monomer properties by use of Bogolirtbov exciton theory (a noii-pert.rirbation method). It was shown earlier that a proper formulation of the theory of CI> for large molecul