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A simple and stereocontrolled syntheses of a 1β-methylcarbapenem key intermediate by means of organosilicon chemistry

✍ Scribed by Shoichiro Uyeo; Hikaru Itani

Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
137 KB
Volume
32
Category
Article
ISSN
0040-4039

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📜 SIMILAR VOLUMES

Simple and highly diastereoselective syn
Simple and highly diastereoselective synthesis of a 1β-methylcarbapenem key intermediate involving divalent tin enolates
✍ Robert Déziel; Denis Favreau 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 199 KB

A simple and diastereoselective synthesis of lS-methylcarbapenem key intermediate has been accomplished via a novel C-C bond formation at the C-4 position of 4-acetoxyazetidinone A involving divalent tin enolates of 3-propanoyl thiazolidine and oxazolidine-Z-thiones derivatives. Carbapenems are amon