Ally1 alcohols can be efficiently carbonylated to /3,y-unsaturated acids or esters in dimethylacetamide (DMA) or MeOH/DMA mixtures under relatively mild conditions (8O"C, 50-100 atm) using a simple catalytic system consisting of palladium iodide in the presence of thiourea as ligand. In the case of
โฆ LIBER โฆ
A simple and mild method for the direct metal-catalyzed carbonylation of allyl alcohols to acids
โ Scribed by Howard Alper; Ibrahim Amer
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 237 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0304-5102
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