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A side condensation reaction of 5-acetoxy-3-chloropentan-2-one with thioformamide involved in the synthesis of vitamin B1

โœ Scribed by M. M. Litvak


Book ID
105585471
Publisher
Springer
Year
1998
Tongue
English
Weight
242 KB
Volume
32
Category
Article
ISSN
0091-150X

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๐Ÿ“œ SIMILAR VOLUMES


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Side Reaction of the Condensation of 5-Acetoxy-3-chloropentanone-2 and Thioformamide in the Synthesis of Vitamin B 1 . -It is shown for the first time that in the cyclocondensation of the title 3-chloropentanone (I) with thioformamide (II), a key step in the vitamin B 1 synthesis, besides the targe

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Concerning a Side Reaction in the Condensation of 5-Acetoxy-3chloropentanone-2 and Thioformamide in the Synthesis of Vitamin B 1 . -The condensation of the title pentanone (I) with in situ formed thioformamide affords a 3-iminomethylthiopentanone intermediate which undergoes cyclocondensation to fur

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