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A Short Stereoselective Preparation of Dienamides from Cyclobutene Compounds. Application in the Synthesis of a New Cyclohexene Nucleoside

✍ Scribed by Gauvry, Noëlle; Huet, François


Book ID
127044650
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
101 KB
Volume
66
Category
Article
ISSN
0022-3263

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Stereoselective rearrangement of 6,7-epoxy-3-oxabicyclo[3.2.0]heptan-2-ones 2 and 3 in water afforded a cisfused butyrolactone as a mixture of two epimers 1a-b. These were used as the starting materials to prepare new bicyclonucleosides 8a-b.