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A short stereocontrolled synthesis of hydroxyethylene dipeptide isosteres

✍ Scribed by Jones, D. Michael; Nilsson, Bo; Szelke, Michael

Book ID
127216654
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
548 KB
Volume
58
Category
Article
ISSN
0022-3263

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Synthesis of hydroxyethylene and ketomet
Synthesis of hydroxyethylene and ketomethylene dipeptide isosteres
✍ Mark W. Holladay; Daniel H. Rich πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 210 KB

A general stereo-directed synthesis of "ketomethylene" and "hydroxyethylene" dipeptide isosteres is reported. Peptides containing the amino acids, (2&%)-5-amino-4-oxo-2,8dimethyloctanoic acid (the "ketomethylene" analog of L-Leu-L-Ala), and (2&,5z)-5-amino-4-hydroxy-2,8-dimethyloctanoic acid (the "h