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A short route to enantiomerically pure narciclasine derivatives

✍ Scribed by M. Khaldi; F. Chrétien; Y. Chapleur

Book ID
103406224
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
232 KB
Volume
36
Category
Article
ISSN
0040-4039

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## Epoxidation with hydrogen peroxide/benzonitrile of (2,!+(2,4/3)-2,3,4-tribcnzyloxycyclohex-5enoneethylene acetal( 13), obtained from methyl 2,3,4-tri-O-benzyl-6-deoxy-a-D-xy[o-hex-5-enopyranoside (9), gave the (2,4/3,5,6)-5,6-anhydride 14 which, with sodium azide in 2-methoxyethanol, gave the (