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A Short Copper–Copper Distance in a (μ-1,2-Peroxo)dicopper(II) Complex Having a 1,8-Naphthyridine Unit as an Additional Bridge

✍ Scribed by Chuan He; Jennifer L. DuBois; Britt Hedman; Keith O. Hodgson; Stephen J. Lippard


Book ID
101365702
Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
107 KB
Volume
40
Category
Article
ISSN
0044-8249

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✦ Synopsis


A copper-copper separation of about 2.84 Å is determined by extended X-ray absorption fine structure studies for the (μ-1,2-peroxo)dicopper(II) species 1, which has only a 1,8-naphthyridine unit as an additional bridge. Complex 1 was prepared by the reaction of O with a dicopper(I) complex formed from BPMAN.


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